Reaction of Sulfenyl Chlorides with Sulfides. IV. The Reaction with 1-Phenylvinyl Sulfides
نویسندگان
چکیده
منابع مشابه
Reaction of Organic Sulfides with Singlet Oxygen. A Revised Mechanism
On the basis of ab initio calculations we propose a revised mechanism for the reaction of organic sulfides with singlet oxygen, which is more consistent with experimental evidence than previous schemes. In aprotic solvents the reagents initially form a weakly bound peroxysulfoxide, with a small barrier due to entropy. The peroxysulfoxide may decay back to ground state (triplet) oxygen, be trapp...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1973
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.46.687